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Karoline Oum

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Aug 5, 2024, 5:54:22 AM8/5/24
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Oneor more protons are present in the nucleus of every atom. They provide the attractive electrostatic central force which binds the atomic electrons. The number of protons in the nucleus is the defining property of an element, and is referred to as the atomic number (represented by the symbol Z). Since each element is identified by the number of protons in its nucleus, each element has its own atomic number, which determines the number of atomic electrons and consequently the chemical characteristics of the element.

The word proton is Greek for "first", and the name was given to the hydrogen nucleus by Ernest Rutherford in 1920. In previous years, Rutherford had discovered that the hydrogen nucleus (known to be the lightest nucleus) could be extracted from the nuclei of nitrogen by atomic collisions.[10] Protons were therefore a candidate to be a fundamental or elementary particle, and hence a building block of nitrogen and all other heavier atomic nuclei.


Free protons occur occasionally on Earth: thunderstorms can produce protons with energies of up to several tens of MeV.[16][17] At sufficiently low temperatures and kinetic energies, free protons will bind to electrons. However, the character of such bound protons does not change, and they remain protons. A fast proton moving through matter will slow by interactions with electrons and nuclei, until it is captured by the electron cloud of an atom. The result is a diatomic or polyatomic ion containing hydrogen. In a vacuum, when free electrons are present, a sufficiently slow proton may pick up a single free electron, becoming a neutral hydrogen atom, which is chemically a free radical. Such "free hydrogen atoms" tend to react chemically with many other types of atoms at sufficiently low energies. When free hydrogen atoms react with each other, they form neutral hydrogen molecules (H2), which are the most common molecular component of molecular clouds in interstellar space.[18]


Protons and neutrons are both nucleons, which may be bound together by the nuclear force to form atomic nuclei. The nucleus of the most common isotope of the hydrogen atom (with the chemical symbol "H") is a lone proton. The nuclei of the heavy hydrogen isotopes deuterium and tritium contain one proton bound to one and two neutrons, respectively. All other types of atomic nuclei are composed of two or more protons and various numbers of neutrons.


In 1886, Eugen Goldstein discovered canal rays (also known as anode rays) and showed that they were positively charged particles (ions) produced from gases. However, since particles from different gases had different values of charge-to-mass ratio (q/m), they could not be identified with a single particle, unlike the negative electrons discovered by J. J. Thomson. Wilhelm Wien in 1898 identified the hydrogen ion as the particle with the highest charge-to-mass ratio in ionized gases.[23]


Following the discovery of the atomic nucleus by Ernest Rutherford in 1911, Antonius van den Broek proposed that the place of each element in the periodic table (its atomic number) is equal to its nuclear charge. This was confirmed experimentally by Henry Moseley in 1913 using X-ray spectra (More details in Atomic number under Moseley's 1913 experiment).


Depending on one's perspective, either 1919 (when it was seen experimentally as derived from another source than hydrogen) or 1920 (when it was recognized and proposed as an elementary particle) may be regarded as the moment when the proton was 'discovered'.


One or more bound protons are present in the nucleus of every atom.Free protons are found naturally in a number of situations in which energies or temperatures are high enough to separate them from electrons, for which they have some affinity. Free protons exist in plasmas in which temperatures are too high to allow them to combine with electrons.[32] Free protons of high energy and velocity make up 90% of cosmic rays, which propagate through the interstellar medium.[33] Free protons are emitted directly from atomic nuclei in some rare types of radioactive decay.[34] Protons also result (along with electrons and antineutrinos) from the radioactive decay of free neutrons, which are unstable.[35]


The spontaneous decay of free protons has never been observed, and protons are therefore considered stable particles according to the Standard Model. However, some grand unified theories (GUTs) of particle physics predict that proton decay should take place with lifetimes between 1031 and 1036 years. Experimental searches have established lower bounds on the mean lifetime of a proton for various assumed decay products.[36][37][38]


Experiments at the Super-Kamiokande detector in Japan gave lower limits for proton mean lifetime of 6.61033 years for decay to an antimuon and a neutral pion, and 8.21033 years for decay to a positron and a neutral pion.[39]Another experiment at the Sudbury Neutrino Observatory in Canada searched for gamma rays resulting from residual nuclei resulting from the decay of a proton from oxygen-16. This experiment was designed to detect decay to any product, and established a lower limit to a proton lifetime of 2.11029 years.[40]


However, protons are known to transform into neutrons through the process of electron capture (also called inverse beta decay). For free protons, this process does not occur spontaneously but only when energy is supplied. The equation is:


The process is reversible; neutrons can convert back to protons through beta decay, a common form of radioactive decay. In fact, a free neutron decays this way, with a mean lifetime of about 15 minutes. A proton can also transform into a neutron through beta plus decay (β+ decay).


The internal dynamics of protons are complicated, because they are determined by the quarks' exchanging gluons, and interacting with various vacuum condensates. Lattice QCD provides a way of calculating the mass of a proton directly from the theory to any accuracy, in principle. The most recent calculations[48][49] claim that the mass is determined to better than 4% accuracy, even to 1% accuracy (see Figure S5 in Drr et al.[49]). These claims are still controversial, because the calculations cannot yet be done with quarks as light as they are in the real world. This means that the predictions are found by a process of extrapolation, which can introduce systematic errors.[50] It is hard to tell whether these errors are controlled properly, because the quantities that are compared to experiment are the masses of the hadrons, which are known in advance.


These recent calculations are performed by massive supercomputers, and, as noted by Boffi and Pasquini: "a detailed description of the nucleon structure is still missing because ... long-distance behavior requires a nonperturbative and/or numerical treatment ..."[51]More conceptual approaches to the structure of protons are: the topological soliton approach originally due to Tony Skyrme and the more accurate AdS/QCD approach that extends it to include a string theory of gluons,[52] various QCD-inspired models like the bag model and the constituent quark model, which were popular in the 1980s, and the SVZ sum rules, which allow for rough approximate mass calculations.[53] These methods do not have the same accuracy as the more brute-force lattice QCD methods, at least not yet.


A value from before 2010 is based on scattering electrons from protons followed by complex calculation involving scattering cross section based on Rosenbluth equation for momentum-transfer cross section), and based on studies of the atomic energy levels of hydrogen and deuterium.In 2010 an international research team published a proton charge radius measurement via the Lamb shift in muonic hydrogen (an exotic atom made of a proton and a negatively charged muon). As a muon is 200 times heavier than an electron, resulting in a smaller atomic orbital, it is much more sensitive to the proton's charge radius and thus allows a more precise measurement.[56] Subsequent improved scattering and electron-spectroscopy measurements agree with the new small radius. Work continues to refine and check this new value.[57]


In 2018 this pressure was reported to be on the order 1035 Pa, which is greater than the pressure inside a neutron star. It was said to be maximum at the centre, positive (repulsive) to a radial distance of about 0.6 fm, negative (attractive) at greater distances, and very weak beyond about 2 fm. These numbers were derived by a combination of a theoretical model and experimental Compton scattering of high-energy electrons.[58][59][60] However, these results have been challenged as also being consistent with zero pressure[61] and as effectively providing the pressure profile shape by selection of the model.[62]


Although protons have affinity for oppositely charged electrons, this is a relatively low-energy interaction and so free protons must lose sufficient velocity (and kinetic energy) in order to become closely associated and bound to electrons. High energy protons, in traversing ordinary matter, lose energy by collisions with atomic nuclei, and by ionization of atoms (removing electrons) until they are slowed sufficiently to be captured by the electron cloud in a normal atom.


However, in such an association with an electron, the character of the bound proton is not changed, and it remains a proton. The attraction of low-energy free protons to any electrons present in normal matter (such as the electrons in normal atoms) causes free protons to stop and to form a new chemical bond with an atom. Such a bond happens at any sufficiently "cold" temperature (that is, comparable to temperatures at the surface of the Sun) and with any type of atom. Thus, in interaction with any type of normal (non-plasma) matter, low-velocity free protons do not remain free but are attracted to electrons in any atom or molecule with which they come into contact, causing the proton and molecule to combine. Such molecules are then said to be "protonated", and chemically they are simply compounds of hydrogen, often positively charged. Often, as a result, they become so-called Brnsted acids. For example, a proton captured by a water molecule in water becomes hydronium, the aqueous cation H3O+.

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