Hi Zoe,
You will see differences with dielectric smoothing (material property averaging) turned on and off, especially with materials that have high dielectric constant. Obviously to test this in the current version of gprMax (v.3.x) these materials cannot have dispersive properties, such as Debye. So yes, if the differences are significant for the examples you are interested in, then having dielectric smoothing with Debye materials maybe useful to you.
Kind regards,
Craig