Hello,
As Cloud SQL is a fully managed service the Superuser is not supported in Cloud SQL [1].
Searching all the flags [2] that are available in order to configure a Cloud SQL instance, it seems that max_logical_replication_workers is not available. I would suggest you to open a feature request [3] asking to implement this as a database flag.
Also another suggestion would be to host your PostgreSQL to Compute Engine that will give you more flexibility [4].
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[1] https://cloud.google.com/sql/docs/postgres/features#unsupported_features
[2] https://cloud.google.com/sql/docs/postgres/flags#list-flags-postgres
[3] https://issuetracker.google.com
[4] https://cloud.google.com/architecture/cloning-a-postgresql-database-on-compute-engine
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