Unfortunately, from your question, I cannot understand your actual situation. So, how about the following patterns?
Pattern 1
When the quantity available is changed by submitting the Google Form, how about modifying the questions of Google Form when the Google Form is submitted?
Pattern 2
When the quantity available is NOT changed by submitting the Google Form and the Spreadsheet is changed by some users and the webhook by Sheets API, how about modifying the questions of Google Form when the Spreadsheet is changed?
If I misunderstood your question and those were not useful, I apologize.