Looks to me like somebody is doing head requests to your app using curl. curl is a command line program that downloads web pages, similar to wget. This particular user is coming from linux, possibly from here: Portugal, Braga, Universidade do Minho (although reverse IP search results aren't always accurate).
If I were you, I'd just ignore the errors. You aren't in business to make some college kid's half-baked web scraper work correctly.
However, if you do want to handle the HEAD requests, you just add a method analogous to the post or get handlers you have implemented already in your main.py.
-Joshua
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