Our next maintenance period is from 6-8pm, but that's a coincidence more than any other reason.
First off, we really want to encourage you to migrate to High Replication. I can't stress this enough. This allows us to do lots of work to App Engine without impacting your application's service. I know some people have been holding off because the blobstore migration tool doesn't exist yet; this is coming.
One of the reasons we like having maintenances at certain times is because of one of App Engine's strengths: it's built using a lot of Google's existing infrastructure (the datastore uses Megastore, which uses BigTable, for instance). By performing maintenance during US/Pacific working hours (or close), we can always ensure that if we need to contact another team, that we can minimize the delay of finding someone at home.
We love High Replication because it lets us hide away all of the work that needs to happen to keep a system as large as App Engine online. Please embrace it!
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Ikai Lan
Developer Programs Engineer, Google App Engine