The *.appspot.com domain name does not use it.
* And/or PSS https://groups.google.com/d/topic/google-appengine/uDqHw-1AFyc/discussion
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One think not noted in that, is the Edge Cache is only used if you use
a Custom Domain - ie via Google Apps*.
http://code.google.com/appengine/articles/domains.html
The *.appspot.com domain name does not use it.
I dont think there is any documentation for the edge cache. But its
well discussed in this group - search the archives.
But its also born out experimentally. Apps Domains are cnamed to
ghs.google.com, which resolves to various locations. Appspot doesnt do
this - like noted in the first post. In effect ghs.google.com is
Googles CDN.
can see this with:
http://www.opendns.com/support/cache/