Hi Steven,
The line you're hitting basically throws an exception if the function "curl_init" isn't available, which occurs when the libcurl extension isn't loaded.
It appears that others are also having issues enabling libcurl with Wamp on stackoverflow.
The following two stackoverflow threads might help steer you in the right direction:
You also want to double check that you're editing the correct php.ini file. You can double check by running:
print get_cfg_var('cfg_file_path');
That will print out the path to your php.ini file. Make sure you're editing that file.