Try to think of "Mediation" and "AdMob Network" as two separate libraries compiled into the same binary.
In the new UI, House ads are treated as a mediation line item. So house ads stats show up in the mediation report. If you have more than one line item on your ad unit, you are essentially using mediation.
Mediation uses a waterfall model. The request goes to the first line item, which logs a mediation request. If it fills, a mediation impression is recorded on that line item. If it doesn't fill, the next network gets a request and a chance to get an impression.
If that mediation line item happens to be AdMob network, request/impressions will also get reported in AdMob network report.
In Thomas's case, his ad unit was migrated from the legacy UI, and has a legacy publisher ID, and a legacy mediation ID associated with his ad unit. @Thomas, did you ever release your app with a publisher ID integrated (not a mediation ID)? If so, than any users who didn't update your app that uses the legacy mediation ID could be generating requests associated with your new AdMob ad unit, but not going through the mediation flow. Therefore, stats could theoretically show up on AdMob report but not through mediation.