I'd recommend at least writing a does-something toy app using only the standard library, to give you some perspective when you evaluate the strengths and weaknesses of any frameworks you come across. Unlike most other languages (and their standard libraries) used for web development, the invention of Go postdates the rise of the modern web (so Go's design has benefited from the clear hindsight of successes and mistakes that other languages have made, and what choices evolved with the web well, and which did not); PHP, Python, Ruby, etc all predate the popularization of the framework concept, and most or all of those languages' standard libraries are very unwieldy for web development. Go's net/http package and its standard library, on its own, is fully capable of handling all common (and most uncommon) aspects of http, including streamlined integration with related technologies, thus unlike with other languages, frameworks don't fulfill a technical "need" in Go, they may only lend some convenience (so it would be incorrect to assume that because other languages "need" frameworks to be effective at web development, Go or some other language X must also need frameworks). Frameworks often have a steeper learning curve then the stdlib -- net/http makes the delegation of responsibilities very clear, but "do everything for you" frameworks can sometimes involve a lot of research or expertise to resolve the question of whether doing something by hand will break the framework, or if there's some hidden way to make the framework do something that it wasn't quite designed for.
Several of the frameworks I've seen made for Go seem to be direct ports of frameworks from other languages, possibly made due to lack of understanding of the Go way of doing things (they like the Go syntax, but don't understand the Go semantics and style) -- frameworks aren't "good" in and of themselves, but can only be good when well coupled with the host language. A general lesson is that a good idea in one language often isn't the best idea in another language, and may often actually be an ineffective solution if blindly carried over (e.g. automatic routing, or script-level page serving may be a good idea in php, but is much less effective in Go, not to say that Go is any less effective as a web-serving language).
To this end, if and when you find the stdlib insufficient for your needs,
http://www.gorillatoolkit.org/, as a "toolkit", is designed to enhance the standard library by adding some convenience functionality, without limiting your flexibility in the name of convenience like most "frameworks" do.
That said, I have never personally been inconvenienced by the standard library, and thus have had little reason to use third party solutions (so at least some of us are ecstatic to use just the included batteries) -- if you're going to use anything effectively, though, you should probably know how to do it using only the stdlib -- at that point you can effectively make an informed decision about what flexibility/convenience tradeoffs are worth the effort, and where, if at all, a given framework will be too limiting.