Further research has identified KOH, NaOH, KI or KMNO4
impregnated activated carbon as a possible H2SO4 removal
technology for airplanes flying above 60ºN with SAI in place. The strong
base scratches the carbon surface, creating chemisorption sites in addition to
those already present for physical adsorption of VOCs.
Most applications and verification studies
have involved SO2, so the applicability to H2SO4,
etc. is inferred and will require laboratory and field validation. But it does appear that combined with moving
the ECS filtration to before the bleed this could solve the problem described
in the paper.
Other problems will result which will have to addressed. The levels of concern are still quite low in
terms of measurement limits. The low
levels may also not result in good removal efficiency which will need to be
determined.
The airlines will have to eat the extra fuel charge due to reduced thrust which is
a small price to pay since the alternative may be not flying at all! Cabin air is generally very low relative
humidity (5-20%) and is why you can easily get dehydrated on a long
flight. If any of these compounds are used,
the cabin air may have to be humidified, otherwise, uptake may be low. Humidification will also increase corrosion. So, there are a number of tradeoffs to be
worked out.
A
commentor asked about background levels of H2SO4 in
ambient air and how this might impact the retrofits and monitoring. While
SO2 levels are generally <25 ug/m3over the U.S. they are much lower above 60ºN. H2SO4
is in the ppt except in areas where sulfur containing volcanic emissions
are found. So, while calculating health risk levels is easy, measuring
them is a different issue.
A Guide To Impregnated Activated Carbon | General Carbon
Corporation

