Ron,
Thanks for asking:
1) Wasn't invited to Calgary.
2) As Socolow et al and more recently House et al. PNAS 108:20428–20433 have shown, if your game is removing CO2 from air, concentrating molecular CO2 from air is probably the last thing you want to do because of the prohibitive thermodynamics and hence cost. But what really irks me about the DAC crowd is they act as though they are inventing air capture, e.g., the Economist article's subtitle that gushes:
"The idea of pulling carbon dioxide out of the atmosphere is a beguiling one. Could it ever become real?"
or Marc Gunther's quote:
"Most scientists believe removing CO2 from the air is expensive and impractical to do on a global scale."
Let me be the first to break the good news; air capture is occurring all around us, to the tune of about 17 Gt CO2/yr. That's right, the equivalent of about 57% of anthro CO2 emissions is thankfully already being removed from air by natural process for free. I'd say that is a pretty good example of effective, low cost, global scale air capture, in contrast to the latest $1000/tonne CO2 figure of House et al. So, if one is interested in increasing air capture, the obvious places to start are figuring out how to 1) increase global photosynthesis (afforestation, ocean fetilization), 2) decrease respiration of biomass (biochar), or my favorite, 3) increasing mineral weathering rates. Then there are hybrids of 1 -3. Why start with a highly artificial and expensive process of concentrating molecular CO2 when nature provides much lower cost and less risky examples that are already in global scale operation?
3) Haven't read Marc's ebook, but assume it's along the lines of the Economist article. Perhaps he'll send me a free, autographed copy
4) See above. I've submitted a followup letter to PNAS, for what that's worth.
5) Good point - why insist on concentrated, molecular CO2 as your end product? Nature doesn't. One has to conclude that EOR is their end game, in which case this generates a net air CO2 source rather than a sink: In standard CO2-EOR, 3 tonnes of CO2 are generated from product per tonne of CO2 injected. You can be sure that oil companies will want to increase (worsen) this 3/1 ratio if they are paying >$100/tonne CO2 injected. Traditional geologic sources of CO2 for EOR are less than 1/10th this cost.
So what is the DAC business model, why is venture capital interested, and what does it have to do with stabilizing air CO2? Any Calgarians care to fill us mortals in?
Your humble messenger,
Greg
Hello Ken,I'm an advocate of direct air capture. I've followed this board for a while and hope this is an opportune moment to comment.My view is that large scale ocean based algae production can provide a geoengineering method that addresses both CO2 capture and solar radiation management, producing commercially valuable fuel, food, fertilizer and fabric in a method that is entirely ecologically sustainable.Algae production can combine the best features of Solar Radiation Management and CO2 Capture in a method that is funded by production of commercial commodities. Algae is the most efficient photosynthesis crop, and can be produced in controlled ocean environments, using energy from tide, wave, current, wind and sun to mimic the original process of deposition of fossil fuel, at very low operating and capital costs, if done on large enough scale.
Please see my description at http://rtulip.net/yahoo_site_admin/assets/docs/Algae_Biofuel_Feedstock_System_Provisional_Patent.285191915.pdfThis is all public domain. I am more concerned about contributing to public goods than anything else. I just want to know if these ideas are feasible, so would welcome expert comment. My estimate is that controlled algae production on 0.1% of the world ocean could stabilise the global climate and deliver a path to steady reduction in CO2 concentration, through sustainable fuel, food, fabric and fertilizer production.Kind RegardsRobert TulipProgram ManagerMining for DevelopmentAustralian Agency for International Development
I participated in the Calgary DAC meeting and in my remarks my primary message was the need to resist the pressure to morph the technology into a commodity CO2 production technique. If DAC earns a reputation as just another industrial gas production technique it will encounter well-deserved opposition.
As to whether DAC has a future as a genuine carbon-negative technology, this is an economic proposition. Currently, it seems pretty expensive but as has been pointed out, the actual costs won’t be known until someone tries it in a real-world context and there may be a role for it to address remaining emissions after all the less expensive options have been deployed. In my view, this argues for a modest R&D program to build a few demo plants.
I understand the temptation for today’s developers to look at the EOR market as a way to do some learning by doing but I believe it is the wrong path to follow. Such a path would create economic relationships that could wind up impeding the policy changes we need to protect the climate, rather than helping to speed those changes.
From a Calgarian mortal to the geoengineering group: My keynote at the Calgary meeting can be found on my website, or simply by clicking on:
http://www.princeton.edu/mae/people/faculty/socolow/12-03-07-Calgary-Summit-keynote.pdf
Rob
for the input.
Here's my problem: The negative evaluations of the artificial concentration of
CO2 from air (CCA?) are being used to pass judgement on all possibilities for
direct air capture of CO2 (DAC) and the uptake portion of carbon dioxide removal
from air (CDR). As the APS and House et al have shown, CCA is probably
irrelevant for DAC/CDR because of the thermodyamics and because it is
concentrating carbon in a form (CO2) that is not benign and has limited
usefulness.
So let's then turn our attention to other DACs and CDR that don't concentrate
CO2 from air, that we know safely and cost-effectively work, and that are
currently operating at something like 17Gt CO2/yr. If pulling an extra 1GT of
CO2/yr is the goal, it would seem much cheaper, safer, and more timely to figure
out how to increase existing, zero-cost, natural DAC by 1/17th (6%), than using
$1000/tonne CCA.
I therefore find statements like the following very misleading:
1) First things first: Virtually all large-scale industrial CO2 sources should
be decarbonized before DAC is deployed.
2) Not only is DAC much more expensive, but DAC requires low-C power to be
carbon-negative.
3) DAC could compensate cost-effectively for the last fractions of fossil fuels
use.
4) DAC may be used someday to reduce the atmospheric CO2 concentration. At very
large scale, it may well compete favorably with biological strategies for CO2
removal."
R. Socolow at Calgary
http://www.princeton.edu/mae/people/faculty/socolow/12-03-07-Calgary-Summit-keynote.pdf
My view:
1) natural DACs are in operation now and are saving our bacon from the full
effects large-scale industrial CO2 sources. It is dangerous and unnecessary to
wait on DAC, esp R&D, until large-scale industrial CO2 sources are mitigated
(when fossil fuel runs out?).
2) natural DACs are low if not zero cost and fractionally scaling them up will
not cost anywhere near the $1000/tonne CO2 price tag as for CCA. DAC via mineral
weathering is exothermic, not energy consuming (excluding mass handing and any
schemes to increase kinetics).
3) natural DACs are very cost effectively (though not completely) compensating
for fossil fuel use right now.
4) ditto. Capacity wise, CCA will never compete for biological CO2 uptake and
doesn't need to. It's interesting to contemplate what modified or synthetic
biology might be able to do (i.e., why not build on a few billion years of CO2
uptake experience rather than start from scratch with CCA?). But the bio C
storage is leaky (unless you use e.g., biochar or CROPS). In any case,
exothermic, geochemical uptake of CO2 is the primary way the earth removes and
safely stores excess CO2. There are ways to accelerate this that may cost
<1/10th that of CCA. The end product of mineral weather can be environmentally
beneficial and could have $$ value.
Bottom line: Please stop equating CCA with all DAC possibilities. The outlook
for DAC is far less depressing than the CCAers have concluded. As in any
potential, large-scale endeavor, the environmental, societal, and economic
impacts of any given DAC approach needs to be evaluated and weighed against
alternative technology/actions. How about an APS style study to address these?
How about a meeting that explores the true DAC possibilities? Angels welcome.
Thanks again and regards,
Greg
" the strong rejection of DAC by Dr. Caldeira", Is this available somewhere? did I miss it?thanksjohn gorman
----- Original Message -----From: rongre...@comcast.netSent: Sunday, March 25, 2012 8:02 PMSubject: Re: [geo] Calgary meeting on Direct Air Capture - thoughts?
" the strong rejection of DAC by Dr. Caldeira", Is this available somewhere? did I miss it?thanksjohn gorman----- Original Message -----From: rongre...@comcast.netSent: Sunday, March 25, 2012 8:02 PMSubject: Re: [geo] Calgary meeting on Direct Air Capture - thoughts?Prof. Socolow, list, etal
1. Thanks for your DAC response (in full below). I have now spent a good bit of time on the excellent Ppt you prepared for the Calgary meeting, and I have also re-read the full APS report.
If anyone has a way of getting more of such Calgary-presented PPt material made available, that would be very helpful. Anyone know of any plans to make more of the Calgary dialog available?
2. We have now had plenty of time for some defense from DAC supporters. It is unfortunate that there has been none. It would seem you have won the battle - but I still hope to hear more from the four DAC corporations or anyone else at the Calgary meeting. I support the strong rejection of DAC by Dr. Caldeira,
" the strong rejection of DAC by Dr. Caldeira", Is this available somewhere? did I miss it?thanksjohn gorman----- Original Message -----From: rongre...@comcast.netSent: Sunday, March 25, 2012 8:02 PMSubject: Re: [geo] Calgary meeting on Direct Air Capture - thoughts?Prof. Socolow, list, etal
1. Thanks for your DAC response (in full below). I have now spent a good bit of time on the excellent Ppt you prepared for the Calgary meeting, and I have also re-read the full APS report.
If anyone has a way of getting more of such Calgary-presented PPt material made available, that would be very helpful. Anyone know of any plans to make more of the Calgary dialog available?
2. We have now had plenty of time for some defense from DAC supporters. It is unfortunate that there has been none. It would seem you have won the battle - but I still hope to hear more from the four DAC corporations or anyone else at the Calgary meeting. I support the strong rejection of DAC by Dr. Caldeira,