Patick,
You said
"Obviously trying to keep the number of different molds to a minimum."
Bingo.
An important part of choosing the right design of a dome (or almost anything, for that matter) is keeping the variation in parts and part size to a minimum. This reduces cost, increases simplicity and makes success more likely.
Firstly, with respect to concrete block domes, if you look, you will specifically see that this was partly addressed in Robert's patent.
https://patents.google.com/patent/US10487494B1/en He discusses using mortar to fill the space between blocks when they are used for a larger or smaller dome, as this changes the dihedral angles. There are other ways to do that, but its a start.
However, there are also some options in design that are very frequently (and sadly) overlooked. Some have been discussed in this forum under various topics. I've been looking at these myself for the creased diamond panel domes I've been evaluating. So let me mention a few here.
1) Pentakis Dodecahedron
This is similar to a 2 frequency Class 2 Method 3 (triacon). The nice part is like the triacon, although all the panels are the same, in the Pent Dod, all the dihedral angles are the same. There are some limits on dome size, but the edge-up configuration provides a nice truncation. Gerry posted some really good material on this.
2) Edge up 3f
A dome that has been popular for decades is the 3f ico alternate. However, one approach few people seem to consider is the edge-up configuration, which provides a flat truncation for a hemisphere. People often bring up the Kruske dome, which has its assets, but low variation in parts is not one of them.
3) Catalan solids
This is an entire class of polyhedrons with this description:
"Catalan solids are a group of thirteen convex polyhedra that are the duals of the Archimedean solids. They are characterized by having faces that are all the same type, constant dihedral angles, and specific symmetry properties, but their vertices are not symmetric."
Excellent resource. There are lots of them if you look.
https://dmccooey.com/polyhedra/https://dmccooey.com/polyhedra/Catalan.htmlhttps://www.qfbox.info/4d/catalan3dhttps://mathworld.wolfram.com/CatalanSolid.htmlThere is more out there, but this is a good start for you and others that understand the value of reducing variation in the structure.
Remember, every success begins with the decision to try.
John F. Kennedy
Let us know if this helps and what else might.
Dx G