Ganesh,
the type of brackets you use is very important. When you use {, it creates a cell array, which is slightly different from a matrix. A cell array allows you to store different types of information in the same cell (for example, I could say a = { [1:10], 'hello',14}, and it would save it as such - a double array, a string and an int. Because of this, plain matrix operations don't generally work with cells the same way they do with matrices. If you use square brackets, however, you create a plain Jane matrix (which you can do all sorts of mathematical operations with), like so:
a = [1,2;3,4]
a =
1 2
3 4
--> a = a.*2
a =
4 8
12 16
Hope this helps!
TJ