I am doing this and it works quite good, but you need to use a separate single-point IR sensor to do the correlation.
For my application, I use a MLX90614 with 5° FOV (BCI or DCI).
To get ambient temperature independant raw values from the Lepton, you need to activate Radiometry mode over I2C. Otherwise, you need to redo the calibration if the ambient temperature changes too much.
For the calibration proccess, I point the IR sensor to the middle of the FOV of the Lepton and then take 100 different samples. That takes about 10 seconds. Afterwards, I use a methamtical method called "Least square fit" to get the first grade calibration formula (y = ax + b)
There are implementations of this method for any programming languages on the web, just google it. As soon as you have the calibration formula, you can then go ahead and calculate the absolute temperature for every pixel on the Lepton ! Of course the accuracy depends on the objects used in the calibration procces, so if you use different hot and cold objects, it should be quite good.
I hope that was helpfull ;)