1) mpiexec is not in your path so when you just type mpiexec it gives the error that it can't find it
2) fds_mpi congfig.txt doesn't work because it is not the correct command. The correct command is as given in the User's Guide using mpiexec
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To view this discussion on the web visit https://groups.google.com/d/msgid/fds-smv/edc913c1-9f47-4ec2-a3c1-10a701c05049%40googlegroups.com.