I would not jump to conclusions so quickly. Yes, certainly check all
the obvious things in your calc, but then consider what FDS is doing,
and then what the Cleary or Heskestad model is doing. FDS is just
transporting smoke from the fire to the vicinity of the detector. So
FDS predicts the time history of smoke concentration and velocity
OUTSIDE of the detector chamber. So at a minimum, look at these
outputs via the DEVC utility. The velocity determines the time lag for
smoke entering the detector: dt = L/u. So, the faster the velocity u,
the shorter the time lag. Maybe the higher ceiling case has a higher
velocity and shorter time lag.
Another thing -- the detector algorithm activates when the chamber
obscuration gets above the given threshold. Maybe in the high ceiling
case you spike above the threshold for some short time.
In any case, consider the quantities that FDS calculates and feeds
into the detector algorithm before reaching a conclusion.