Not that this should cause an instability, but you do not need to specify CO as a lumped component. And you should not use a special FORMULA for propane. Just specify FUEL='PROPANE' and then FDS will use the correct propane thermochemical properties.
Do you have sealed domains with pressure zones? This is likely the cause of an instability. The systems have to be perfectly mass balanced; make sure there is a path to an OPEN boundary. And lastly, you might try using the ULMAT pressure solver, as this eliminates mass errors at zone boundaries.