Thank you for your answer; I hadn't considered that issue. I thought of another possibility to solve my problem. I attempted to create my own 'air' species for the background and set the absorption coefficient to achieve the same effect as explained in the first message. I also set the emissivity of this new 'air' to 0 because I'm only interested in the flame, not the air contribution. However, I tried this approach following the instructions in the liquid droplet section of the User Guide (15.3).
&SPEC ID='MY AIR', EMMISSIVITY=0 ,RADIATIVE_PROPERTY_TABLE='radtab' [...] /
&TABL ID='radtab', TABLE_DATA= 1.0,0.00001,0.00001 /
&TABL ID='radtab', TABLE_DATA= 5.0,0.00001,0.00001 /
&TABL ID='radtab', TABLE_DATA= 5.1,100000,0.00001 /
&TABL ID='radtab', TABLE_DATA= 5.2,0.00001,0.00001 /
&TABL ID='radtab', TABLE_DATA=10.0,0.00001,0.00001 /
I tried it anyway, and FDS returned an error indicating that it was not well defined. It was predictable as the RADIATIVE_PROPERTY_TABLE is for PART and not SPEC... but i did not find anything similar fot SPEC. Do I have to use a RadCal species as a base for radiation properties? Is it impossible to create a completely new species or a species that doesn't match any of RadCal's existing ones?
Also, note that it is not important for me that the air react with the fuel of the flame.