From the User's Guide: October 29, 2010 FDS Version 5.5 SVNRepository
Revision : 6997
Section 14.3.4
"The output quantity THERMOCOUPLE is the temperature of a modeled
thermocouple. The thermocouple temperature lags the true gas
temperature by an amount determined mainly by its bead size."
Thermocouple temperature is different than the gas temperature based
on the energy balance on the thermocouple bead as given in Equation
14.13