There is no limit to the HRRPUA you can specify other than eventually a high enough HRRPUA will violate the low-speed flow limitation of FDS.
Fuel does not burn until it can mix with air.
If you have no fuel coming out of the burner the temperature at the center of the burner will be ambient
If you have a very small flow rate, it will fully mix with air in the first grid cell above the burner and burn there resulting in an increased temperature.
As you increase the flow rate, as long as it is still fully mixing in that first grid cell, the temperature will continue to increase.
At some point the fuel flow rate will be large enough that it no longer can burn in the first grid cell. Some of it will have to be transported further away before it burns. This excess fuel will act as a diluent and temperatures will begin to drop.