&REAC FUEL='ETHANOL VAPOR'
FYI='Ethanol, C_2 H_6 O'
HEAT_OF_COMBUSTION = 26780.
O=1.
C=2.
H=6.
SOOT_YIELD=0.008 /
Here you are telling FDS your fuel is ETHANOL vapor.
&MATL ID = 'ETHANOL LIQUID'
EMISSIVITY = 1.0
NU_SPEC = 0.97
SPEC_ID = 'ETHANOL'
HEAT_OF_REACTION=836.98
CONDUCTIVITY=0.17
SPECIFIC_HEAT= 2.4398
DENSITY= 789.
ABSORPTION_COEFFICIENT = 1534.3
BOILING_TEMPERATURE=78.5 /
Here you are telling FDS you are evaporating ETHANOL.
The names do not match so you have two different species, the fuel you are evaporating does not match the name in your REAC. Since ETHANOL is a predefined species and you are using simple chemistry you don't need the SPEC line and your REAC line can just be:
&REAC FUEL='ETHANOL'
SOOT_YIELD=0.008 /