1. I don't think I have seen radiative fraction data for very large wood fires.
2. The radiative fraction just applies to cells where there is a heat release rate.
3. Those gasses plus fuel and any other gas species where a RADCAL species is specified on SPEC for that gas.
4. It may be that the default path length used to generate the absorptivities for the radiation transport is too small. OPTICALLY_THIN will be a conservative answer. You could try increasing the default path length. You could also set HUMIDTY=0 and Y_CO2_INFTY=0 on MISC which would still let smoke absorb radiation but prevent the ambient air around the fire from absorbing radiation..