What, precisely, are you looking at "in station" for your comparison?
Buy and sell volumes are the total volume of that item currently in open buy or sell orders, respectively. It's not related to the total amount traded over time - that information is not available, since there's no way via the EVE API to tell the difference between an order being fulfilled and an order expiring or being cancelled.
EVE Central also doesn't update instantly, so in faster-moving markets things in station may well have changed since EVE Central last pulled data.
Hope that's useful.
James