Unfortunately, ETE has no direct support for Nexus format :(
from ete2 import Tree
t = Tree()
t.populate(10)
# Export as simple Nexus
tree_name = "MyTree"
print "#NEXUS\nBEGIN TREES;"
print "tree '%s' = %s" %(tree_name, t.write())
print "END;"
If you plan to include alignment and tree in the same file, you will need to add some more lines to the code. It should not be difficult for simple datasets.
Jaime