If you want accuracy you will need to calibrate both shunts starting with the battery one. To do so you need to have a two fixed current limits say a 10A as that is probably the max your multi meter can measure and 1A as the low value.
So say the SBMS self consumption is 0.8W (WiFi ON) battery voltage 26V then 0.8W / 26V = 0.030A so your battery current shunt will indicate -0.030A probably will fluctuate 2 to 3 bit so depending on current shunt each bit is 9mA or 6mA
Then when you add 1A exactly as load you should read -1.030A and with 10A you will read 10.030A if not then you need to modify the current shunt value to match this measurement Say you use the 150A current shunt your default value will be 0.5000mOhm so if you read say less than 10A when you know for sure you have exactly 10A trough the shunt say you read 9.900A that will be 1% error then you can just change the resistance live probably 0.4950 in this example will provide you with the correct reading.
Once that battery current shunt is calibrated you will calibrate the PV shunt based on the battery shunt that is now calibrated so say you have the 100A current shunt there so 0.7500 by default and say this time you have 10A or even 20A coming from PV panels not important what current value you get just disconnect all loads and just have the PV current that way the current trough the PV shunt will be exactly equal with current
trough battery shunt and then adjust the PV shunt value until PV current matches battery current exactly then you will have no discrepancy between the current shunts as they re both properly calibrated.
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Once again, connect your charger so SBMS controls it or you'll get distracted and overcharge your cells.
After it's done test it to see it's actually working. Then leave SBMS0 do it's job. When connected first time soc starts from 50% as there is no way SBMS to know where your battery is. So it might get to 100% and still be at 60% real or jump fom 55% to 100% in one sec. After the first charge (any cell gets to 3,55v) the soc is set to 100% and from there should be ok. If you didn't let the SBMS to complete at least one charge soc will not be correct and there is chance your settings are correct. Just let SBMS do it job.