What is the exact model of that BlueSeas relay ?
The SBMS0 EXT IOx outputs are all optoisolated and they will be either Open circuit (for OFF) or Close circuit (for ON) and max current allowed when close circuit is 50mA.
The SBMS0 requires that charge sources are controlled ON/OFF separately from loads and SBMS0 needs to be able to control ON/OFF all Loads and separately all charge sources else it can not protect the battery.
I do not know what model of Midnite MPPT you have but some have a AUX port that can be configured to be able to be controlled by an external BMS. The SBMS0 needs to control ON/OFF your MPPT as the MPPT has no idea when to stop charging as it can not see the individual cell voltages.