LiFePO4 will only need bulk charging after that charging will need to be stopped as battery is full. And alternators are just not designed to deal with battery being disconnected.
Thus people have a small starter battery Lead Acid and from there a battery to battery charger to charge the LiFePO4
Not sure that Balmar can handle being disconnected from battery but I guess you can try. In any case charging from alternator should be avoided as it is so extremely expensive at around 50x more than charging from solar PV.
PV has cost amortization done for around 25 years but since alternator charging is 50x more expensive that means if you where to charge from alternator for half a year then cost will be the same as the cost of PV panels that where able to provide that same energy and from there PV panels will still last 25 years thus 50x cost difference is very extreme and this only considers the fuel cost not the alternator or other equipment.