Connecting them in series (either the 500W or 620W) will exceed the voltage rating of the DSSR20.
The 500W panels is best for charging a 24V battery using DSSR20 or DSSR50 if you need energy most in hot summer days. Else if you need most of the energy in colder days (cloudy or winter) then even the 54 cell (108 half cell) models will do even better.
Not sure if bi-facial panels will offer any advantage if installed on the roof of your RV here is an example of 108 half cell panel LONGi LR8-54HGBB-500M You can expect about 16A from that panel at STC it may peak at 18A in some conditions so it will be a good choice for one DSSR20.
I still have a few DSSR20's if you need more than 4 I just do not have the spacer PCB's (can order a few of those but will take time).