Venus may look nice from Earth but it has a very hot atmosphere with sulfuric acid droplets "Venus's atmosphere consists mainly of carbon dioxide, with clouds of sulfuric acid droplets. Only trace amounts of water have been detected in the atmosphere. The thick atmosphere traps the sun's heat, resulting in surface temperatures over 880 degrees Fahrenheit (470 degrees Celsius). Probes that have landed on Venus have not survived more than a few hours before being destroyed by the incredibly high temperatures." (National Geographic) ("Venus"). Living on Venus would be extremely difficult with all of that acidic rain and heat. I suppose NASA could come up with some kind of Venus anti-atmospheric suit but I doubt that would happen any time soon.
Mars is more ideal for landing but the mountains can make it difficult"But probing the mountain will be the vehicle’s primary focus. At roughly 5 kilometers (16,400 feet), Sharp rises higher above the landscape than does any mountain in the continental United States. It’s built from layer upon layer of mineral-rich materials. Some cays in it would seem to have required water to form. So as Curiosity moves by, it will shoot out a laser beam at the mountain and then direct on-board chemical samplers to “taste” the vaporized rock. Another on-board device can drill into rock, pulverizing it into a fine powder for the rover’s chemical samplers to taste." (Janet Raloff) ("Curiosity Lands on Mars") Mars has rich soil, large creators and high cliffs... This can make it hard for rovers to travel the terrain.
Overall Mars would be more ideal to land on due to Venus's extreme hot atmosphere, acidic rain and volcanic activity. Mars does have a few obstacles such as mountains and craters but curiosity is built to easily scale the mountains and safely climb down cliffs.