If you are trying to connect using TLS then you must use the turns: protocol not turn: The rest looks correct. Although there many other settings that have to be right including realm.
If set right you should get something like this in the turnserver log
1389880891: handle_turn_command: user <>: request BINDING processed, error 0
1389880891: IPv4. tcp or tls connected to: ipaddr:port
1389880891: handle_turn_command: user <>: message processed, error 401
1389880891: new Allocation: id=0xd150d5ee, username=<username>, lifetime=600
Also make sure UDP is properly blocked to the remote browser otherwise you may still have a UDP path to the peer, which will never fall back to TURN. Are you testing in real world scenarios or inside the same network?
Chrome will use a configured HTTP proxy, but the proxy server must support the connect method on the port used. So 443 should be fine here.