Ashes 2009 Highly Compressed For Pc
Geri Cutcher
Volcanic ash consists of fragments of rock, mineral crystals, and volcanic glass, produced during volcanic eruptions and measuring less than 2 mm (0.079 inches) in diameter.[1] The term volcanic ash is also often loosely used to refer to all explosive eruption products (correctly referred to as tephra), including particles larger than 2 mm. Volcanic ash is formed during explosive volcanic eruptions when dissolved gases in magma expand and escape violently into the atmosphere. The force of the gases shatters the magma and propels it into the atmosphere where it solidifies into fragments of volcanic rock and glass. Ash is also produced when magma comes into contact with water during phreatomagmatic eruptions, causing the water to explosively flash to steam leading to shattering of magma. Once in the air, ash is transported by wind up to thousands of kilometres away.
Due to its wide dispersal, ash can have a number of impacts on society, including animal and human health, disruption to aviation, disruption to critical infrastructure (e.g., electric power supply systems, telecommunications, water and waste-water networks, transportation), primary industries (e.g., agriculture), buildings and structures.
Volcanic ash is also produced during phreatomagmatic eruptions. During these eruptions fragmentation occurs when magma comes into contact with bodies of water (such as the sea, lakes and marshes) groundwater, snow or ice. As the magma, which is significantly hotter than the boiling point of water, comes into contact with water an insulating vapor film forms (Leidenfrost effect).[7] Eventually this vapor film will collapse leading to direct coupling of the cold water and hot magma. This increases the heat transfer which leads to the rapid expansion of water and fragmentation of the magma into small particles which are subsequently ejected from the volcanic vent. Fragmentation causes an increase in contact area between magma and water creating a feedback mechanism,[7] leading to further fragmentation and production of fine ash particles.
Pyroclastic density currents can also produce ash particles. These are typically produced by lava dome collapse or collapse of the eruption column.[8] Within pyroclastic density currents particle abrasion occurs as particles violently collide, resulting in a reduction in grain size and production of fine grained ash particles. In addition, ash can be produced during secondary fragmentation of pumice fragments, due to the conservation of heat within the flow.[9] These processes produce large quantities of very fine grained ash which is removed from pyroclastic density currents in co-ignimbrite ash plumes.
Physical and chemical characteristics of volcanic ash are primarily controlled by the style of volcanic eruption.[10] Volcanoes display a range of eruption styles which are controlled by magma chemistry, crystal content, temperature and dissolved gases of the erupting magma and can be classified using the volcanic explosivity index (VEI). Effusive eruptions (VEI 1) of basaltic composition produce 109 m3) of ejecta into the atmosphere.[11]
The principal gases released during volcanic activity are water, carbon dioxide, hydrogen, sulfur dioxide, hydrogen sulfide, carbon monoxide and hydrogen chloride.[12] The sulfur and halogen gases and metals are removed from the atmosphere by processes of chemical reaction, dry and wet deposition, and by adsorption onto the surface of volcanic ash.
It has long been recognised that a range of sulfate and halide (primarily chloride and fluoride) compounds are readily mobilised from fresh volcanic ash.[13][14] It is considered most likely that these salts are formed as a consequence of rapid acid dissolution of ash particles within eruption plumes, which is thought to supply the cations involved in the deposition of sulfate and halide salts.[15]
The crystalline-solid structure of the salts act more as an insulator than a conductor.[20][21][22][23] However, once the salts are dissolved into a solution by a source of moisture (e.g., fog, mist, light rain, etc.), the ash may become corrosive and electrically conductive. A recent study has shown that the electrical conductivity of volcanic ash increases with (1) increasing moisture content, (2) increasing soluble salt content, and (3) increasing compaction (bulk density).[23] The ability of volcanic ash to conduct electric current has significant implications for electric power supply systems.
Volcanic ash particles erupted during magmatic eruptions are made up of various fractions of vitric (glassy, non-crystalline), crystalline or lithic (non-magmatic) particles. Ash produced during low viscosity magmatic eruptions (e.g., Hawaiian and Strombolian basaltic eruptions) produce a range of different pyroclasts dependent on the eruptive process. For example, ash collected from Hawaiian lava fountains consists of sideromelane (light brown basaltic glass) pyroclasts which contain microlites (small quench crystals, not to be confused with the rare mineral microlite) and phenocrysts. Slightly more viscous eruptions of basalt (e.g., Strombolian) form a variety of pyroclasts from irregular sideromelane droplets to blocky tachylite (black to dark brown microcrystalline pyroclasts). In contrast, most high-silica ash (e.g. rhyolite) consists of pulverised products of pumice (vitric shards), individual phenocrysts (crystal fraction) and some lithic fragments (xenoliths).[24]
Ash generated during phreatic eruptions primarily consists of hydrothermally altered lithic and mineral fragments, commonly in a clay matrix. Particle surfaces are often coated with aggregates of zeolite crystals or clay and only relict textures remain to identify pyroclast types.[24]
The morphology (shape) of volcanic ash is controlled by a plethora of different eruption and kinematic processes.[24][25] Eruptions of low-viscosity magmas (e.g., basalt) typically form droplet shaped particles. This droplet shape is, in part, controlled by surface tension, acceleration of the droplets after they leave the vent, and air friction. Shapes range from perfect spheres to a variety of twisted, elongate droplets with smooth, fluidal surfaces.[25]
The morphology of ash from eruptions of high-viscosity magmas (e.g., rhyolite, dacite, and some andesites) is mostly dependent on the shape of vesicles in the rising magma before disintegration. Vesicles are formed by the expansion of magmatic gas before the magma has solidified. Ash particles can have varying degrees of vesicularity and vesicular particles can have extremely high surface area to volume ratios.[24] Concavities, troughs, and tubes observed on grain surfaces are the result of broken vesicle walls.[25] Vitric ash particles from high-viscosity magma eruptions are typically angular, vesicular pumiceous fragments or thin vesicle-wall fragments while lithic fragments in volcanic ash are typically equant, or angular to subrounded. Lithic morphology in ash is generally controlled by the mechanical properties of the wall rock broken up by spalling or explosive expansion of gases in the magma as it reaches the surface.
The morphology of ash particles from phreatomagmatic eruptions is controlled by stresses within the chilled magma which result in fragmentation of the glass to form small blocky or pyramidal glass ash particles.[24] Vesicle shape and density play only a minor role in the determination of grain shape in phreatomagmatic eruptions. In this sort of eruption, the rising magma is quickly cooled on contact with ground or surface water. Stresses within the "quenched" magma cause fragmentation into five dominant pyroclast shape-types: (1) blocky and equant; (2) vesicular and irregular with smooth surfaces; (3) moss-like and convoluted; (4) spherical or drop-like; and (5) plate-like.
Volcanic ash consists of particles (pyroclasts) with diameters less than 2 mm (particles larger than 2 mm are classified as lapilli),[1] and can be as fine as 1 μm.[10] The overall grain size distribution of ash can vary greatly with different magma compositions. Few attempts have been made to correlate the grain size characteristics of a deposit with those of the event which produced it, though some predictions can be made. Rhyolitic magmas generally produce finer grained material compared to basaltic magmas, due to the higher viscosity and therefore explosivity. The proportions of fine ash are higher for silicic explosive eruptions, probably because vesicle size in the pre-eruptive magma is smaller than those in mafic magmas.[1] There is good evidence that pyroclastic flows produce high proportions of fine ash by communition and it is likely that this process also occurs inside volcanic conduits and would be most efficient when the magma fragmentation surface is well below the summit crater.[1]
Ash particles are incorporated into eruption columns as they are ejected from the vent at high velocity. The initial momentum from the eruption propels the column upwards. As air is drawn into the column, the bulk density decreases and it starts to rise buoyantly into the atmosphere.[8] At a point where the bulk density of the column is the same as the surrounding atmosphere, the column will cease rising and start moving laterally. Lateral dispersion is controlled by prevailing winds and the ash may be deposited hundreds to thousands of kilometres from the volcano, depending on eruption column height, particle size of the ash and climatic conditions (especially wind direction and strength and humidity).[28]
Ash fallout occurs immediately after the eruption and is controlled by particle density. Initially, coarse particles fall out close to source. This is followed by fallout of accretionary lapilli, which is the result of particle agglomeration within the column.[29] Ash fallout is less concentrated during the final stages as the column moves downwind. This results in an ash fall deposit which generally decreases in thickness and grain size exponentially with increasing distance from the volcano.[30] Fine ash particles may remain in the atmosphere for days to weeks and be dispersed by high-altitude winds. These particles can impact on the aviation industry (refer to impacts section) and, combined with gas particles, can affect global climate.
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