Hi Deepak,
Is it that you'd like to capture change events when the contents of an actual materialized view in Postgres (as defined via CREATE MATERIALIZED VIEW ...) have changed? If so, it'd depend on whether these changes will be published by Postgres to logical decoding plug-ins as the one used by Debezium. I haven't tried that out, but I suppose that this is probably not the case. Instead, you'd have to capture changes from the tables on which the view is sourced and update you own "view" in some sink DB.
--Gunnar