Hi Soon,
The class you want is FE_Nedelec. PolynomialsNedelec is used to generate the basis set. However, I would be wary of using it in 3D domains where you cannot guarantee that the cells are of standard orientation. That basically means that you need to stick to meshes which are essentially cube-like.
There are a few example which I and others have posted in this user group. For the real-valued equation there's a fairly simple real 3D implementation within the tests for the current development version, see here
https://github.com/dealii/dealii/blob/master/tests/deal.II/nedelec_non_rect_face.ccTo handle the complex-valued equation you describe, you'd need to use an FE_System with two FE_Nedelec elements and decompose things into real/imaginary parts in order to build the linear system.
I'm currently working on an implementation which I think will overcome the orientation issues, but I wouldn't rely on it being ready very soon.
Best of luck,
Ross