If you need to group multiple images into one series, you'd need to create multiple dicom files (one for each image), each with the same Study Instance UID, the same Series Instance UID and differen SOP Instance UIDs (i.e. the image's UID). You should be able to send the Dicom files in any order, and a good PACS should be able to group them, based on the UIDs.
Hope that helps ;)