Hi Margherita,
in CP2K, all MPI routines are gathered in a wrapper that you can find in "src/mpiwrap/message_passing.F". For examples where MPI_WAIT and MPI_WAITALL are called, I suggest you grep for "mp_wait" and "mp_waitall".
Best,
Augustin
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-- Augustin Bussy Postdoctoral researcher Hutter Group University of Zurich