Hi Sreenivas,
The short answer is that we haven't yet made out of the box CoreOS image work with multiple networks. You can certainly try to write the service files yourself. Here are some things to keep in mind:
1. In the multi-network case, flanneld will no longer signal systemd about its readiness ("READY=1") so you will not be using "Type=notify" anymore (this b/c there's no longer one single READY event).
3. If you're using Docker, you will either need to pick a single network for it or run multiple Docker daemons. Then, use DOCKER_HOST or "docker -H ..." to pick the daemon when running a container.
-Eugene