Dicrepancy between calculated and called specific enthalpy values for hydrogen

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Tuur Knevels

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Aug 3, 2023, 11:35:16 AM8/3/23
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Hello there,

I'm trying to calculate properties at various stages in a hydrogen based system.
Typically I try to find mass specific enthalpy using the following command:
 

Screenshot 2023-08-03 172819.png

which works fine.

In a different section I also find the mass specific coefficient of constant pressure, cp:
Screenshot 2023-08-03 173017.png
This also works find and give realistic values.

However, in a later stage I found a discrepancy when I calculate a different variable based on either h or cp

To my understanding h = cp*T. But when I calculate the mass specific enthalpy in this manner, multiplying the called value of cp with the temperature it was called for, I find a different value for h. In total scope the difference is small but unfortuately nog negligible.

Calculating the dh in a different way and finding the delta:
Screenshot 2023-08-03 173240.png
H_diff_lst results
Screenshot 2023-08-03 173251.png

Could somebody explain this discrepancy to me?
Or direct me to which one is more correct, the cp value or the H value?

Thank you in advance!

Ian Bell

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Aug 3, 2023, 12:29:49 PM8/3/23
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First off,  please read the first FAQ: https://github.com/CoolProp/CoolProp/blob/master/FAQ.md 

In short, h is not equal to cp*T. A change in enthalpy can be approximated, but only approximated, as cp*T

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