Original author of the HD emulation here. Better late than never, eh?
I picked slot 7 for a few reasons, the first was that the other slots were already taken by useful devices. I also preferred the hard drive booting over the floppy drive, and as the IIe's boot code scans from slot 7 down to 1, slot 7 became the only viable choice for bootable Prodos volumes.
I think having it listen for a few thousand cycles for open-apple to be held down then divert to slot 6 is really the best, and, honestly, most accurate to historic hardware. There isn't much room left in the firmware image, but I think there might be just enough.