I get MinGW-w64 there:
https://sourceforge.net/projects/mingw-w64/files/Toolchains%20targetting%20Win32/Personal%20Builds/mingw-builds/
https://sourceforge.net/projects/mingw-w64/files/Toolchains%20targetting%20Win64/Personal%20Builds/mingw-builds/
Notice there is one distribution for 32 bits compilers, another for 64 bits. They come with gcc, g++ and gfortran, but not the Ada compiler.
For a given version (say 7.1.0, currently the last), there are 8 files, one for each combination of 32/64 bits, POSIX/Windows threads, and SEH/longjump exception handling. Appart from the bit-ness, I don't think the choice is relevant for Fortran programming.
However, if you are using precompiled third party libraries, it may be important. For instance, tha LAPÄCK for Windows distribution requires a specific combination. I never remember which, but you can find out by checking the DLL imports of LAPACK's DLL.
Also, last time I checked, this LAPACK DLL was compatible with gfortran 6.3.0 and earlier versions, but not 7.1.0, because of the libgfortran version.
Another point to consider: some projects come with their own distribution of the gcc suite. For instance R, Ruby (until recently) and Strawberry Perl. If you are developing Fortran DLLs for R, consider using Rtools instead of MinGW-w64, as it comes with additionnal utilities. Notice R comes with LAPACK, so you don't need to look for it elsewhere.
Last remark: with MinGW-w64 you get only the compilers. If you need a more complete toolchain, you may try MSYS2 in addition to MinGW-w64. I have successfully used it to compile the GSL library, among others.
http://www.msys2.org/
HTH
Jean-Claude Arbaut