Ferro Materials Pte Ltd
Apolito Ghosh
Ferromagnetism is a property of certain materials (such as iron) that results in a significant, observable magnetic permeability, and in many cases, a significant magnetic coercivity, allowing the material to form a permanent magnet. Ferromagnetic materials are noticeably attracted to a magnet, which is a consequence of their substantial magnetic permeability.
Magnetic permeability describes the induced magnetization of a material due to the presence of an external magnetic field. For example, this temporary magnetization inside a steel plate accounts for the plate's attraction to a magnet. Whether or not that steel plate then acquires permanent magnetization depends on both the strength of the applied field and on the coercivity of that particular piece of steel (which varies with the steel's chemical composition and any heat treatment it may have undergone).
In physics, multiple types of material magnetism have been distinguished. Ferromagnetism (along with the similar effect ferrimagnetism) is the strongest type and is responsible for the common phenomenon of everyday magnetism.[1] An example of a permanent magnet formed from a ferromagnetic material is a refrigerator magnet.[2]
Permanent magnets (materials that can be magnetized by an external magnetic field and remain magnetized after the external field is removed) are either ferromagnetic or ferrimagnetic, as are the materials that are attracted to them. Relatively few materials are ferromagnetic. They are typically pure forms, alloys, or compounds of iron, cobalt, nickel, and certain rare-earth metals.
Ferromagnetism is vital in industrial applications and modern technologies, forming the basis for electrical and electromechanical devices such as electromagnets, electric motors, generators, transformers, magnetic storage (including tape recorders and hard disks), and nondestructive testing of ferrous materials.
Ferromagnetic materials can be divided into magnetically soft materials (like annealed iron), which do not tend to stay magnetized, and magnetically hard materials, which do. Permanent magnets are made from hard ferromagnetic materials (such as alnico) and ferrimagnetic materials (such as ferrite) that are subjected to special processing in a strong magnetic field during manufacturing to align their internal microcrystalline structure, making them difficult to demagnetize. To demagnetize a saturated magnet, a magnetic field must be applied. The threshold at which demagnetization occurs depends on the coercivity of the material. Magnetically hard materials have high coercivity, whereas magnetically soft materials have low coercivity.
Historically, the term ferromagnetism was used for any material that could exhibit spontaneous magnetization: a net magnetic moment in the absence of an external magnetic field; that is, any material that could become a magnet. This definition is still in common use.[3]
Ferromagnetism is an unusual property that occurs in only a few substances. The common ones are the transition metals iron, nickel, and cobalt, as well as their alloys and alloys of rare-earth metals. It is a property not just of the chemical make-up of a material, but of its crystalline structure and microstructure. Ferromagnetism results from these materials having many unpaired electrons in their d-block (in the case of iron and its relatives) or f-block (in the case of the rare-earth metals), a result of Hund's rule of maximum multiplicity. There are ferromagnetic metal alloys whose constituents are not themselves ferromagnetic, called Heusler alloys, named after Fritz Heusler. Conversely, there are non-magnetic alloys, such as types of stainless steel, composed almost exclusively of ferromagnetic metals.
Amorphous (non-crystalline) ferromagnetic metallic alloys can be made by very rapid quenching (cooling) of an alloy. These have the advantage that their properties are nearly isotropic (not aligned along a crystal axis); this results in low coercivity, low hysteresis loss, high permeability, and high electrical resistivity. One such typical material is a transition metal-metalloid alloy, made from about 80% transition metal (usually Fe, Co, or Ni) and a metalloid component (B, C, Si, P, or Al) that lowers the melting point.
A relatively new class of exceptionally strong ferromagnetic materials are the rare-earth magnets. They contain lanthanide elements that are known for their ability to carry large magnetic moments in well-localized f-orbitals.
Most ferromagnetic materials are metals, since the conducting electrons are often responsible for mediating the ferromagnetic interactions. It is therefore a challenge to develop ferromagnetic insulators, especially multiferroic materials, which are both ferromagnetic and ferroelectric.[8]
In 2009, a team of MIT physicists demonstrated that a lithium gas cooled to less than one kelvin can exhibit ferromagnetism.[12] The team cooled fermionic lithium-6 to less than 150 nK (150 billionths of one kelvin) using infrared laser cooling. This demonstration is the first time that ferromagnetism has been demonstrated in a gas.
Recent research has shown evidence that ferromagnetism can be induced in some materials by an electric current or voltage. Antiferromagnetic LaMnO3 and SrCoO have been switched to be ferromagnetic by a current. In July 2020, scientists reported inducing ferromagnetism in the abundant diamagnetic material iron pyrite ("fool's gold") by an applied voltage.[15][16] In these experiments, the ferromagnetism was limited to a thin surface layer.
One of the fundamental properties of an electron (besides that it carries charge) is that it has a magnetic dipole moment, i.e., it behaves like a tiny magnet, producing a magnetic field. This dipole moment comes from a more fundamental property of the electron: its quantum mechanical spin. Due to its quantum nature, the spin of the electron can be in one of only two states, with the magnetic field either pointing "up" or "down" (for any choice of up and down). Electron spin in atoms is the main source of ferromagnetism, although there is also a contribution from the orbital angular momentum of the electron about the nucleus. When these magnetic dipoles in a piece of matter are aligned (point in the same direction), their individually tiny magnetic fields add together to create a much larger macroscopic field.
However, materials made of atoms with filled electron shells have a total dipole moment of zero: because the electrons all exist in pairs with opposite spin, every electron's magnetic moment is cancelled by the opposite moment of the second electron in the pair. Only atoms with partially filled shells (i.e., unpaired spins) can have a net magnetic moment, so ferromagnetism occurs only in materials with partially filled shells. Because of Hund's rules, the first few electrons in an otherwise unoccupied shell tend to have the same spin, thereby increasing the total dipole moment.
When two nearby atoms have unpaired electrons, whether the electron spins are parallel or antiparallel affects whether the electrons can share the same orbit as a result of the quantum mechanical effect called the exchange interaction. This in turn affects the electron location and the Coulomb (electrostatic) interaction and thus the energy difference between these states.
Although the exchange interaction keeps spins aligned, it does not align them in a particular direction. Without magnetic anisotropy, the spins in a magnet randomly change direction in response to thermal fluctuations, and the magnet is superparamagnetic. There are several kinds of magnetic anisotropy, the most common of which is magnetocrystalline anisotropy. This is a dependence of the energy on the direction of magnetization relative to the crystallographic lattice. Another common source of anisotropy, inverse magnetostriction, is induced by internal strains. Single-domain magnets also can have a shape anisotropy due to the magnetostatic effects of the particle shape. As the temperature of a magnet increases, the anisotropy tends to decrease, and there is often a blocking temperature at which a transition to superparamagnetism occurs.[21]
The spontaneous alignment of magnetic dipoles in ferromagnetic materials would seem to suggest that every piece of ferromagnetic material should have a strong magnetic field, since all the spins are aligned; yet iron and other ferromagnets are often found in an "unmagnetized" state. This is because a bulk piece of ferromagnetic material is divided into tiny regions called magnetic domains[22] (also known as Weiss domains). Within each domain, the spins are aligned, but if the bulk material is in its lowest energy configuration (i.e. "unmagnetized"), the spins of separate domains point in different directions and their magnetic fields cancel out, so the bulk material has no net large-scale magnetic field.
Ferromagnetic materials spontaneously divide into magnetic domains because the exchange interaction is a short-range force, so over long distances of many atoms, the tendency of the magnetic dipoles to reduce their energy by orienting in opposite directions wins out. If all the dipoles in a piece of ferromagnetic material are aligned parallel, it creates a large magnetic field extending into the space around it. This contains a lot of magnetostatic energy. The material can reduce this energy by splitting into many domains pointing in different directions, so the magnetic field is confined to small local fields in the material, reducing the volume of the field. The domains are separated by thin domain walls a number of molecules thick, in which the direction of magnetization of the dipoles rotates smoothly from one domain's direction to the other.
Thus, a piece of iron in its lowest energy state ("unmagnetized") generally has little or no net magnetic field. However, the magnetic domains in a material are not fixed in place; they are simply regions where the spins of the electrons have aligned spontaneously due to their magnetic fields, and thus can be altered by an external magnetic field. If a strong-enough external magnetic field is applied to the material, the domain walls will move via a process in which the spins of the electrons in atoms near the wall in one domain turn under the influence of the external field to face in the same direction as the electrons in the other domain, thus reorienting the domains so more of the dipoles are aligned with the external field. The domains will remain aligned when the external field is removed, and sum to create a magnetic field of their own extending into the space around the material, thus creating a "permanent" magnet. The domains do not go back to their original minimum energy configuration when the field is removed because the domain walls tend to become 'pinned' or 'snagged' on defects in the crystal lattice, preserving their parallel orientation. This is shown by the Barkhausen effect: as the magnetizing field is changed, the material's magnetization changes in thousands of tiny discontinuous jumps as domain walls suddenly "snap" past defects.
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