Cosima,
there are usually many processes that are usually neglected..
I presume most people think of the losses as coronal losses for which what we have in CHIANTI is OK and PE is not relevant (at the surface).
PE would be most relevant for the chromosphere, where actually
CHIANTI is a bit limited.
We are in the process to include several other processes in CHIANTI,
which affect the transition region and chromosphere mostly.
In the future we will also add photoionization, which might be
important for you, depending on what kind of stars you want to model..
Giulio