Deepak,
the
obvious thing to do is to calculate the contribution function
G(T)
for the two lines, then you take the ratio and get the
isothermal
temperature. Or if you have more lines you can plot the
EM
loci curves, i.e. plot I/G(T) for the lines, the crossing will give
you
the ionisation temperature (cf. Del Zanna & Mason living review)
Giulio