If you run the file from CEdit, go to the "Output Tab," select the checkbox next "Validation Output," then just click "Run" to run the file. Output for smoke should then be in mg/m^3.
To run from the command line, run the Windows Command Prompt (it's usually in the folder "Windows Accessories" on the Start Menu, or type "CMD" in the search box on the taskbar, change to the folder where the input file is, then run CFAST as described in Appendix D of the CFAST User's Guide with the -v option