The problem in Sandcastle is caused by your image coordinates are invalid. Longitude must be in the range -180 to 180 degrees. Latitude must be in the range -90 to 90 degrees. Even so, after editing the image to remove extraneous data and modifying the KML to give the image coordinates to be at the limits there are a couple of problems in Cesium (I'll submit issues if none exist already).
1. I had to adjust the image coordinates to be -90.0 to 90.0 and -179.9999 to 180.0 to get the image to display.
2. The image is displayed improperly (all white).
I found KML files at
www.gadm.org, but be warned, the borders are extremely detailed and result in very large files. For example, the USA file is about 65 MB uncompressed. The presentation is filled polygons.
Scott