You can't as the Cassia SessionID does not hold the SID as a property. I use the following, using System.DirectoryServices.AccountManagement. I use
VB.NET but this could simply be used in any other .net language.
Imports System.DirectoryServices.AccountManagement
Imports CassiaDim Domain As
<define class here>
Dim Domain As String = "CONTOSO"
Dim DomainDN As String = "DC=contoso,DC=com"
Dim DomainContext As New PrincipalContext(ContextType.Domain, Domain, DomainDN)
Dim TSServer As ITerminalServer
Dim TSManager As New TerminalServicesManager()
TSServer = TSManager.GetLocalServer()
For Each Session As ITerminalServicesSession In TSServer.GetSessions
Console.WriteLine("Sid: " & UserPrincipal.FindByIdentity(DomainContext, IdentityType.SamAccountName, Session.UserName).Sid.ToString)
Next