[...] With potentially delayed CO2-mitigation efforts, net-negative CO2-emissions may be required
to return to acceptable limits of climate warming as defined by the Paris Agreement. The
ocean is an important CO2 sink under increasing atmospheric pCO2, when physico-chemical
CO2-uptake dominates. The processes that govern its role under net-negative CO2-emission
regimes are, however, unclear. Here we assess changes in marine CO2-uptake and storage
mechanisms under a range of idealized temperature-overshoot scenarios in an Earth System
model of intermediate complexity over centennial timescales. We show that while the fate
of CO2 from physical-chemical uptake is very sensitive to future atmospheric boundary
conditions, storage associated with the biological carbon pump continues to increase and
may even dominate marine excess CO2 storage on multi-centennial time scales. Since change
in biological pump carbon is strongly linked to the oxygenation status of the ocean,
improved prediction of marine deoxygenation turns out to be a key to better forecast the
future of the marine carbon sink on multi-centennial time scales.[...]