When you play to a Chromecast group in BubbleUPnP, the group is entirely a black box for the app:
from its POV, it plays to a unique renderer and it is Google magic that actually plays to multiple CCAs of the group.
That's why a log file would not help as the app doesn't know if individual devices of the group are actually outputting audio or not.
I suppose you may already have looked at that, but when you play to the group (and only 1 CCA is outputting audio),
start the Google Home app and verify that the volume of the silent CCAs of the group is not 0 or muted.
Also, you can try to delete the group and recreate it entirely, just in case it fixes the problem (although unlikely).