You need to have both 2.4 and 5Ghz running on the Deco otherwise your meshing will not be working to its full potential and the B2 will not see a Wi-Fi signal it can connect to on the Deco.
By all means turn both frequencies off on the Hitron but that's most easily done by putting the Hitron in modem only mode.
You can then leave your Deco in router mode and connect all your devices to the Deco Network (SSID).
They will then all be getting their IP addresses from the DECO DHCP server and be on the same network subnet
Another thought....
From what I have read, the Sonos network information and the Sonos proprietary device topology is stored under a Sonos account and (I assume) the information is mirrored to all Sonos devices known to that account.
I also assume that the Brennan software uses an API to read that information and uses it to make its Sonos functionality work, including the the display listing of Sonos destinations.
As Fred said, the Brennan software is talking to the Sonos system not to the individual devices.
As Steve said, if you have a new Wi-Fi network (SSID) its necessary to add all the Sonos devices to that new network.
The Sonos configuration documentation also talks about removing Wi-Fi networks.
I wonder whether if you do not remove the old Wi-Fi network from your Sonos system, then in an environment where there are two different SSID's being broadcast, each with a DHCP server offering different subnet IP address ranges, and both of which are known to the Sonos devices there is an opportunity for network misconnection ?
If you are still having problems telling your Sonos system to forget your original network might help ?
John