Thanks to all who have responded to my original query.
I had not seen the thread that Fred highlighted in the most recent post.
I have investigated further with the following results.
1. I use Exact Audio Copy (EAC) to rip CDs to FLAC files and then use the Upload function to move them to my B2.
What I hadn't realised is that EAC is tagging album art to my FLAC files and that on occasions the databases it uses are not necessarily 100% accurately using the album art relevant to the CD version being ripped.
2. When I have uploaded an album I add the album art using the B2 UI (pasting into the album title details bottom right). I still use the original Web UI .
The B2 creates a file COVERART.PNG in the tracks folder for the album on the B2 HDD and this is what it retrieves for that album when you view the track listing in the bottom right box.
3. When a track is played the B2 retrieves any tagged album art from the track's FLAC file metadata if its there, if not it uses the COVERART.PNG file for the album. This is what is displayed in the track playing box top left.
4. I used MP3TAG to manually change the cover art tag on one track of an album and this confirmed the above as the art changed for that one track when played after another track from the same album.
I now understand better what the B2 is doing.
Thanks to all